Substitution of chemical products used for radiography fixation and developing with a digital system

Number

299-EN

Section

General Section

Use

Sector

Health services

Function

Photochemical
X-Ray Absorber

Process

Use of functional fluids in small devices
Other

Product category

Photo-chemicals

Application

Substitution of chemical products used for radiography fixation and developing

Abstract

The radiology service of the hospital Parc Taulí, Spain, used several chemical products for fixing and developing X-rays. These products, widely used in hospitals, contain hydroquinone, which is carcinogenic and a neurotoxic and boric acid which is an endocrine disrupter. In 2004 these products were replaced by a digitised radiography system. This is a display of digital medical imaging for diagnostic use with a range of software called RAIM.

Substituted substances

Hydroquinone

CAS No. 123-31-9 EC No. 204-617-8 Index No. 604-005-00-4

Chemical group

Phenols

Classification: hazard statements

H351 Suspected of causing cancer
H341 Suspected of causing genetic defects
H302 Harmful if swallowed
H318 Causes serious eye damage
H317 May cause an allergic skin reaction
H400 Very toxic to aquatic life

Boric acid

CAS No. 10043-35-3 EC No. 233-139-2 Index No. 005-007-00-2

Chemical group

Boron compounds; inorganic acids

Classification: hazard statements

H360FD May damage fertility. May damage the unborn child

Other adverse effects

The substance is: endocrine disruptor cat. 1 (EU EDC database), as listed in the Substance Database according to SUBSPORT Screening Criteria (SDSC).

Reliability of information

Evidence of implementation: there is evidence that the solution was implemented and in use at time of publication

Reason substitution

other toxic effects
CMR
skin/respiratory sensitizing
ecotoxicity

Other type of alternative

Digitised radiography system, consisting of a display of digital medical imaging for diagnostic use with a range of software called RAIM (Radiological Archive and Image Management).

Hazard Assessment

Substances to be substituted: Substituted products contained hydroquinone and boric acid . Hydroquinone may cause an allergic skin reaction, according to Annex VI of Regulation (EC) No 1272/2008 (CLP Regulation). It fulfils the criteria to be listed in the Substance Database according to SUBSPORTplus Screening Criteria (SDSC). Boric acid is a Substance of very high concern and is included on the REACH candidate list for authorization, according to Article 59 of Regulation (EG) No. 1907/2006. (REACH Regulation). These risks are eliminated due to the digitised radiography system. Alternative substances Non-chemical alternative

Description of Substitution

The radiology services of the Parc Taulí Hospital in Spain, used several products for fixing and developing radiographies. These chemicals became a hazardous waste which had to be disposed of properly. The fixing product contained hydroquinone, a carcinogenic, mutagenic and sensitizing substance. It also contained boric acid, Which is a reprotoxicant and a suspected endocrine disrupter. In 2004, the hospital decided to replace this process by a digitised radiography system, consisting in a display of digital medical imaging for diagnostic use with a range of software called RAIM (Radiological Archive and Image Management). In addition to conventional radiography, RAIM programs provide support for multiple types of scans: Computed tomography (CT), magnetic resonance imaging, nuclear medicine, etc.. All these electronically scanned images can be printed on plastic material, if required, using a laser printer.

Advantages

  • Elimination of the risk of exposure to hazardous chemicals.
  • Reduction of the environmental impact due to the minimization in waste generation
  • Immediate access to full information of the patients’ tests. Integration with other hospital information systems that manage the activities and workflows.
  • Possibility to share, simultaneously, reviews and diagnosis.
  • Increase in diagnostic performance (comparison of different data scans with different criteria and graphical layouts; possibility of using different monitors and distances, angles and elliptical areas; making measurements, expansion and / or reduction of the image, signal strength, possibility of displaying images individually or in series, modification of the grey levels of the images, etc.).
  • Avoidance of unnecessary travels for patients and professionals (improved work organization).
  • Reduction of the loss of documentation and of space for storing files. Easy retrieval of stored information.
  • Significant cost savings (it can be used with any Windows-compatible computer, which makes the system affordable).

Case/substitution evaluation

The substitution is very positive as it eliminates health and environmental risks, by hydroquinone and boric acid and avoids the need to manage hazardous waste, which also saves money.

State of implementation

Full capacity

Date and place of implementation

2004, Spain

Enterprise using the alternative

https://www.tauli.cat/udiat/usuaris/contacte

Availability of Alternative

On the market

Type of information supplier

User

Contact

See enterprise using the alternative.

Further information

AGFA Revelador (only available in Spanish) https://www.electromedical.net/revelador-agfa-manual-g150-para-6l-12x6l-p-1-50-1004-o-8/">https://www.electromedical.net/revelador-agfa-manual-g150-para-6l-12x6l-p-1-50-1004-o-8/">https://www.electromedical.net/revelador-agfa-manual-g150-para-6l-12x6l-p-1-50-1004-o-8/

Date, reviewed

November 26, 2021