Case story database

Search for Successfully Implemented Alternatives

You can use the free text search function to find information in the case story database. Most suitable are: substance name and other substance identifier (EC- and CAS-number). You can refine your search after first entry for sector-, function- and process-categories. The case studies are meant to serve as source of inspiration and ideas for substitution. The alternatives are constantly being developed further. We therefore recommend that you to check in each individual case whether an alternative is suitable for your applications and purposes. If you are aware of any other relevant information that is not mentioned in the current case story, please contact SUBSPORTplus.

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Substitution von Toluol, Xylol und Naphtha als Lösungsmittel zur Reinigung von Werkzeugen in einer Autowerkstatt

Dieses Fallbeispiel beschreibt die Substitution von „Safety Clean“ (ein universelles Lösungsmittel, bestehend aus Toluol, Xylol, Naphtha und anderen Inhaltsstoffen). Das Entfettungsmittel wurde in einer Autowerkstatt zur Reinigung von Arbeitswerkzeugen eingesetzt.

Substitution of toluene, xylene and naphtha as solvents for cleaning tools in garages

This case study describes the substitution of Safety Clean (a universal solvent consisting of toluene, xylene, naphtha and other ingredients). The degreasing agent was used in a garage for cleaning work tools.

Coating for industrial washing machines - from binder based on epoxy/polyester to polyester

A Danish company produces industrial washing machines. They substituted a paint based on epoxy/polyester with a paint based on polyester. This new product is not classified and is much better than the former used product, the technical performance is better and the energy consumption lower, which probably counterbalances a higher price.

Alternatives to 2-methoxyethanol as put forward by the European Chemicals Agency (ECHA)

This document concerns the general toxicity of 2-methoxyethanol and some common alternatives to its use in different applications. The most common substitutes for 2-methoxyethanol are: PGME, EGBE, ethylene glycol monopropyl ether (EGPE) and their acetates (PGMEA, EGBEA, EGPEA). The decision which alternative to use depends on what application 2-methoxyethanol is currently used in.

Different ways to phase out halocarbons like dichloromethane in various applications.

This document describes how a large portion of the halocarbons used and manufactured in Sweden were phased out during the late 1980´s and early 1990´s. Several specific examples are mentioned concerning what chemicals were substituted and what the alternatives were. The chemicals discussed are mainly: dichloromethane, trichloroethylene, 1,1,2-Dichloro-1,2,2-trifluoroethane and 1,1,1-trichloroethane.

Substitution of sulphuric acid with hydrochloric acid for degreasing metal before zinc and chromium plating.

Metallic coating on metal parts is often performed by galvanic processes. To achieve good-looking surfaces of good quality it is necessary to first clean the items. Earlier the company used sulphuric acid for pickling. The acid was heated and therefore some of it evaporated from the tank. By substituting sulphuric acid with hydrochloric acid pickling not only became more efficient, moreover, hydrochloric acid does not need to be heated.

Galvanic processes with acid zinc instead of cyanide zinc.

An electroplating company in Denmark made changes in the production process for galvanising. They substituted zinc cyanide by zinc chloride.

Chemical treatment of rubber, wood, leather or metal which protects, preserves and renews the surface of the material. An alternative to carbon black.

This document describes a process for protecting, preserving and renewing surfaces, especially rubber and other natural and synthetic polymers including wood, leather, painted surfaces and metal. The material to be treated is soaked with an aqueous solution of substituted or unsubstituted dimethylpolysiloxane. This is done in several stages with other solutions such as diethylene glycol and/or glycerine. This treatment reduces the impact of deleterious effects such as ozone, ultraviolet radiation and environmental causes to the appearance of especially rubber parts used for example in automobiles.

Surface treatment of metals and plastic

This document describes the best available techniques for surface treatment of metals and plastics. Substitution possibilities for EDTA, PFOS, zinc cyanide, copper cyanide and hexavalent chromium are mentioned.

Alternative to thorium oxide in welding rods

Thorium dioxide is used in electric welding as additive to tungsten refractive rods. One of thorium isotopes is hazardous, because is radioactive, therefore alternatives were sought.

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